磁流变液制备的最新进展

介绍了一种新型的智能材料－磁流变液的性能，并对磁流变液的主要组成成分进行了分类总结，阐述了磁流变液制备的最新发展的情况。另外简要介绍了磁流变液应用的方向。     

生长条件对KDP晶体中散射颗粒的影响

利用透射电子显微技术对不同条件下生长的KDP晶体中包裹物进行了观察并测量了其相应尺寸。结果表明，晶体中的生长缺陷、pH值、生长速度和杂质与KDP晶体散射颗粒的形态存在密切关系。     

羰基铁类随机混合吸波材料等效电磁参数的计算

本文为计及多重散射偶极子间的相互作用，引入参量εｈ和μｈ，导得一组公式。它不仅能计算铁氧体类也能计算羰基铁类的随机混合吸波材料的等效电磁参数，均与实验结果吻合良好。     

Ti/Al Interaction and Austenite Grain Control in Crankshaft Manufacturing with 38MnSiVS5 Steel

38MnSiVS5 steel is similar to 38MnVS6 steel (EN), the difference being the addition of a small Ti content. Typical Ti and Al contents in the chemical composition of 38MnSiVS5 steel are Ti=0.020 and Al=0.035 mass%. Both elements combine easily with nitrogen, especially Ti, and it has been observed that relatively high Al levels are harmful for austenite grain size control at reheating temperatures. In this work 38MnSiVS5 steel is used to manufacture a large number of castings, varying only the Ti and Al contents and obtaining ingots with a different Ti/Al ratio in each case. The results show that abnormal growth of the austenitic grain occurs irrespective of the Ti and Al contents, due fundamentally to the partial dissolution and coarsening of TiN precipitates. However, the steels with high Al contents present worse behaviour due to the formation of a second type of precipitates, namely AIN, which quickly dissolve between 1000 and 1100°C, causing a drastic decline in local pinning forces that gives rise to more pronounced abnormal growth of the affected grains.     

A Micellar Route to Ordered Arrays of Magnetic Nanoparticles: From Size‐Selected Pure Cobalt Dots to Cobalt–Cobalt Oxide Core–Shell Systems

Starting with Co‐salt‐loaded inverse micelles, which form if the diblock copolymer polystyrene‐block‐poly(2‐vinylpyridine) is dissolved in a selective solvent like toluene and CoCl₂ is added to the solution, monomicellar arrays of such micelles exhibiting a significant hexagonal order can be prepared on top of various substrates with tailored intermicellar distances and structure heights. In order to remove the polymer matrix and to finally obtain arrays of pure Co nanoparticles, the micelles are first exposed to an oxygen plasma, followed by a treatment in a hydrogen plasma. Applying in‐situ X‐ray photoelectron spectroscopy, it is demonstrated that: 1) The oxygen plasma completely removes the polymer, though conserving the original order of the micellar array. Furthermore, the resulting nanoparticles are entirely oxidized with a chemical shift of the Co 2p_3/2 line pointing to the formation of Co₃O₄. 2) By the subsequent hydrogen plasma treatment the nanoparticles are fully reduced to metallic Co. 3) By exposing the pure Co nanoparticles for 100 s to various oxygen partial pressures pequation/tex2gif-inf-5.gif, a stepwise oxidation is observed with a still metallic Co core surrounded by an oxide shell. The data allow the extraction of the thickness of the oxide shell as a function of the total exposure to oxygen (pequation/tex2gif-inf-7.gif × time), thus giving the opportunity to control the ferromagnetic–antiferromagnetic composition of an exchange‐biased magnetic system.     

Composition and morphology of char particles of fly ashes from industrial burning of high-ash coals with different reactivity

A comparative investigation of the composition and the morphology of char particles was conducted: char particles were recovered from fly ashes of two power stations in Russia from burning of high- and low-reactivity high-ash coals; the known results of studies of char particles generated in laboratory conditions from coals characterized according to the ASTM D388-98a standard were also used. The composition of organic and mineral components of different fraction char particles was studied. An inverse correlation between the content of the organic substance and the iron content in char particles was identified. The morphology of the char particles for the three main types (Cenospheric, Network and Solid) and the influence of coal reactivity and temperature on char morphology were investigated. The morphology of the mineral component of char particles of the two varieties of coals was also studied. It was shown that the high-temperature of industrial burning of Ekibastuz coal results in melting of the mineral substance and forming of micron-scale microspheres located in the lamellar porous structure of the carbon matrix.     

Relation between microstructure, properties and spark plasma sintering (SPS) parameters of pure ultrafine WC powder

A combined experimental/numerical methodology is developed to fully consolidate pure ultrafine WC powder under a current-control mode. Three applied currents, 1900, 2100 and 2700 A, and a constant pressure of 20 MPa were employed as process conditions. The developed spark plasma sintering (SPS) finite-element model includes a moving-mesh technique to account for the contact resistance change due to sintering shrinkage and punch sliding. The effects of the heating rate on the microstructure and hardness were investigated in detail along the sample radius from both experimental and modeling points of view. The maximum hardness (2700 HV10) was achieved for a current of 1900 A at the core sample, while the maximum densification was achieved for 2100 and 2700 A. A direct relationship between the compact microstructure and both the sintering temperature and the heating rate was established.     

Effect of thermophoresis on particle deposition rate from a natural convection flow onto a vertical wavy plate

This research discusses the impacts of the surface area that the wavy surface gets more than the flat plate upon the aerosol particle deposition. Starting from the full Navier–Stokes equation, the mathematical analysis takes the thermophoretic motion formed by the temperature gradient and the fluid thermal expansion into consideration, and converts the governing equations into the boundary layer equation by the simple coordinate transformation and non-similarity method, and then works out these equations by the Spline Alternating-Direction Implicit method (SADI). The numerical value result reveals that the average deposition effect of the wavy plate is greater than the flat plate and that the increasing rate is nearly equal to the value obtained by dividing the surface area that the wavy plate gets more than the flat plate by 2.2.     

WC含量对弥散强化铜Cu/WC组织与性能影响的研究

对以WC粒子为第二相的弥散强化铜材料的组织与性能进行了研究。在同样条件下，用机械混料方法制备了不同WC含量的Cu/WC复合材料，分别测定了其密度，电阻率和硬度，结果表明：WC粒子是一种较为理想的弥散相，并且WC体积含量为1.2%时，细小的球形状第二相粒子均匀分布，弥散效果好，材料密度，硬度较高，而电阻率较小，综合性能较好。